Selective Hydrogenation of Pyridine and Derivatives of It on Bimetallic Catalysts Modified with Chitosan

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Resumo

A study is performed of the catalytic properties of bimetallic nanoparticles based on palladium and a base metal (silver or copper) supported on alumina modified with chitosan in the selective hydrogenation of pyridine and derivatives of it with the formation of piperidine and derivatives of it. It is shown that the effect of increasing the activity of bimetallic nanoparticles is due to the small size of particles (2–3 nm), compared to the monometallic palladium catalyst. It is established that the conversion of pyridine reaches 99% with 99% selectivity toward piperidine under mild conditions (60°C; H2 pressure, 70 atm).

Sobre autores

A. Kustov

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; Moscow State University

Email: kyst@list.ru
119991, Moscow, Russia; 119991, Moscow, Russia

S. Dunaev

Moscow State University

Email: kyst@list.ru
119991, Moscow, Russia

E. Finashina

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: kyst@list.ru
119991, Moscow, Russia

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Declaração de direitos autorais © А.Л. Кустов, С.Ф. Дунаев, Е.Д. Финашина, 2023